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DC Field | Value | Language |
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dc.contributor.author | MUFAKKAR, MUHAMMAD | - |
dc.date.accessioned | 2017-11-30T03:50:57Z | - |
dc.date.accessioned | 2020-04-14T22:51:57Z | - |
dc.date.available | 2020-04-14T22:51:57Z | - |
dc.date.issued | 2009 | - |
dc.identifier.uri | http://142.54.178.187:9060/xmlui/handle/123456789/10103 | - |
dc.description.abstract | A series of Copper(I) complexes with thiones of the general formula [CuaLbScXd](H2O)e and [CuaLbSc]Xd.(H2O)e (where a = 1 - 6, b = 1 - 6, c = 0 - 6, d = 0 - 6, e = 0 - 1 and X = Cl, Br & I) were prepared and characterized by elemental, IR and NMR (1H and 13C) spectroscopic methods. Crystal structures of nine complexes, [Cu(Metu)4]Cl 1, [Cu4(Dmtu)4(S)(μ-S)Cl]Cl.(H2O) 2, [Cu(DeTu)Cl]3 3, [Cu(Metu)4]Br 4, [Cu(Dphtu)2Br]H2O 5, ([Cu(Metu)]I)6 6, [Cu(Mtu)4]I 7, [Cu(Detu)3I] 8 and [Cu(Dbtu)3I]0.6(H2O) 9 were determined by single crystal x-ray diffraction. An upfield shift in the >C=S resonance of thiones in 13 C-NMR and downfield shift in the N-H resonance in 1H-NMR were consistent with the sulfur coordination of thiones to Copper(I). The crystal structures of 1, 4, 7, 8 and 9 show that they are monomeric having tetrahedral or distorted tetrahedral geometries at Copper(I) center. The crystal structure of 2 showed that it consists of a tetrameric cationic complex having terminal as well as doubly bridged Dmtu and S ligands. The complex has two kinds of coordination environments around four Copper atoms, a distorted tetrahedral and a trigonal planer. [Cu(Detu)Cl]3 is a trinuclear complex consisting of Cu3S3 six-membered ring possessing chair conformation. The geometry around each Cu center was nearly trigonal planar. In 5, the Cu(I) atom adopts a slightly distorted trigonal planar coordination. The X-ray studies of 6 showed that the complex was hexanuclear consisting of [Metu-Cu-I] units. The geometry around each Cu center was distorted tetrahedral. In all these complexes intra or/and intermolecular hydrogen bonding is present in 2-D or 3-D network. The antimicrobial activities of Copper(I) bromide complexes were evaluated by minimum inhibitory concentrations (MIC) and they showed wide range of activity against the test isolates. | en_US |
dc.description.sponsorship | Higher Education Commission Islamabad, Pakistan | en_US |
dc.language.iso | en | en_US |
dc.publisher | GC UNIVERSITY LAHORE | en_US |
dc.subject | Natural Sciences | en_US |
dc.title | SYNTHESIS AND CHARACTERIZATION OF COPPER(I) COMPLEXES WITH THIONES | en_US |
dc.type | Thesis | en_US |
Appears in Collections: | Thesis |
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