Please use this identifier to cite or link to this item: http://localhost:80/xmlui/handle/123456789/14336
Title: KINETICS AND MECHANISM OF REDUCTION OF Fe (III) SALICYLATE COMPLEX BY HYDROQUINONE
Authors: WAQAR, DILSHAD
HUSSEIN, WAQAR
Keywords: (Sal) represent - O-C6H4-COO
kobs, observed rate constant
Issue Date: 6-Jan-2011
Publisher: Karachi: Faculty of Pharmacy & Pharmaceutical Sciences, Karachi
Citation: Waqar, D., & Hussein, W. (2011). Kinetics and mechanism of reduction of Fe (III) Salicylate complex by hydroquinone. Pakistan Journal of Pharmaceutical Sciences, 24(1), 31-36.
Abstract: The violet color complex FeSal+ was prepared by reaction of Salicylic acid and Ferric Chloride in acidic medium up to pH 3.5 in formate buffer at ionic strength 0.1 M. Reduction kinetics of FeSal+ complex at pseudo first order condition have been studied spectrophotometrically by a reductant i.e. Hydroquinone. Reduction behaviour shows that reduction is much fast and pH dependent. A mechanism to account for observation is also proposed along with the rate law.
URI: http://142.54.178.187:9060/xmlui/handle/123456789/14336
ISSN: 1011-601X
Appears in Collections:Issue 01

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