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http://142.54.178.187:9060/xmlui/handle/123456789/19193| Title: | Kinetics of the Thermal Gas—phase Decomposition of 2—Ethoxypropene |
| Authors: | IFTIKHAR A. AWAN M.C.Flowers |
| Issue Date: | 20-Sep-1988 |
| Publisher: | HEJ Research Institute of Chemistry, University of Karachi, Karachi. |
| Citation: | Awan, I. A., & Flowers, M. C. (1988). KINETICS OF THE THERMAL GAS-PHASE DECOMPOSITION OF 2-ETHOXYPROPENE. JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 10(3), 363-368. |
| Abstract: | Ki netics of the gas phase deconposition of 2-ethoxypropene has been studied over the temperature range 544-635 K at a pressure between 3 and 72 torr. Ethene and propanone, fomed in equimolar amunt ( ± 4 Z), were the major products and accounted for of the total reaction. These products are forned by homogeneous, non-radical , pathways with the high pressure rate constant given by the equation: -1 12.51±0 .25 -1 = 10 exp(-184.6 ± 2.8 KJ The other products identified were n-butane, 2-rrethy1prop-2-ena1 , bu tanone and 2-pentanone in ratios of approxirrntely 0.01 0.015 : 0.03 : 0.07 relative to ethene respectively. The kinetics and "Echanims for the formation of these products are discussed in detail . |
| URI: | http://142.54.178.187:9060/xmlui/handle/123456789/19193 |
| ISSN: | 0253-5106 |
| Appears in Collections: | Issue 03 |
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| ViewByVolume.aspx?v=144&i=VOLUME%2010,%20NO3,%20SEPT%201988.htm | 150 B | HTML | View/Open |
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