Kinetics of the Thermal Gas—phase Decomposition of 2—Ethoxypropene

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Title:	Kinetics of the Thermal Gas—phase Decomposition of 2—Ethoxypropene
Authors:	IFTIKHAR A. AWAN M.C.Flowers
Issue Date:	20-Sep-1988
Publisher:	HEJ Research Institute of Chemistry, University of Karachi, Karachi.
Citation:	Awan, I. A., & Flowers, M. C. (1988). KINETICS OF THE THERMAL GAS-PHASE DECOMPOSITION OF 2-ETHOXYPROPENE. JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 10(3), 363-368.
Abstract:	Ki netics of the gas phase deconposition of 2-ethoxypropene has been studied over the temperature range 544-635 K at a pressure between 3 and 72 torr. Ethene and propanone, fomed in equimolar amunt ( ± 4 Z), were the major products and accounted for of the total reaction. These products are forned by homogeneous, non-radical , pathways with the high pressure rate constant given by the equation: -1 12.51±0 .25 -1 = 10 exp(-184.6 ± 2.8 KJ The other products identified were n-butane, 2-rrethy1prop-2-ena1 , bu tanone and 2-pentanone in ratios of approxirrntely 0.01 0.015 : 0.03 : 0.07 relative to ethene respectively. The kinetics and "Echanims for the formation of these products are discussed in detail .
URI:	http://142.54.178.187:9060/xmlui/handle/123456789/19193
ISSN:	0253-5106
Appears in Collections:	Issue 03

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