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http://142.54.178.187:9060/xmlui/handle/123456789/19560| Title: | Synthesis and Characterization of the Nickel and Cobalt Complexes of New BF2+ Bridged, 1,2-Benzoquinone Bis (a-Dioxime) Macrocycles |
| Authors: | AHMAD S. ABUSHAMLEH MUSTAFA M. EL-ABADELAH |
| Issue Date: | 8-Dec-2000 |
| Publisher: | Karachi: International Centre for Chemical and Biological Sciences, H.E.J. Research Institute of Chemistry, University of Karachi |
| Citation: | Abushamaleh, A. S., & El-Abadelah, M. M. (2000). Synthesis and characterization of the nickel and cobalt complexes of new BF2+ bridged, 1, 2-benzoquinone bis (alpha-dioxime) macrocycles. JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 22(4), 293-298. |
| Abstract: | The synthesis, characterization and structure of new cobalt and nickel complexes with a BF2+ bridged, bis (1,2-dione dioxime) ligand based on benzoquinone are described. The crystal structure of the bis (BF2+) bridged nickel complex has space group C2/c (#15) with unit cell dimensions a = 19.000 (2), b = 5.452 (2), c = 16.357 (1) A,Beta = 119.251 (7)degrees, V = 1519.8 (2) A(3), Z = 4, R-i = 0.043 and wR(2) = 0.052. The ligand provides strong field and the complexes are diamagnetic. The spectral properties of the complexes are discussed. |
| URI: | http://142.54.178.187:9060/xmlui/handle/123456789/19560 |
| ISSN: | 0253-5106 |
| Appears in Collections: | Issue 04 |
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|---|---|---|---|---|
| 1731-7718-1-RV.htm | 123 B | HTML | View/Open |
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