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Please use this identifier to cite or link to this item: http://142.54.178.187:9060/xmlui/handle/123456789/19580
Title: Thermoanalyticil Studies of Some Schiff Base Polymers and Their Metal Chelates
Authors: M. Y. KHUHAWAR
A. H. CHANNAR
S. W. SHAH
Issue Date: 4-Mar-2000
Publisher: The Chemical Society Of Pakistan
Citation: Khuhawar, M. Y., Channar, A. H., & Shah, S. W. (2000). Thermoanalytical studies of some Schiff base polymers and their metal chelates. JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 22(1), 14-17.
Abstract: Thermogravimetry (TO) and differential thermal analysis (DTA) of poly S,S·· methylene-bis-salicylaldehyde-tetramethylenediimine (PMSATen). poly 5,5' -methylene-bis­salicylaldehyde-meso-stilbenediimine (meso-PMSAS). poly 5, 5'-methylene-bis-salicylaldehyde­dl·stilbenediimine (dl-PMSAS). Poly 5, 5.methylene-bis-salicylaldehycle-2.6-diiminopyridine (PMSAP), and their copper (II) and nickel (II) chelates were recorded in nitrogen atmosphere up to 800 °C. Loss in weight occurs in two to three stages. The polymers and their nickel chelates indicate better thermal stability as compared to their corresponding copper complexes. DT A shows a series of endotherms with maximum in the range of 400-700 °C.
URI: http://142.54.178.187:9060/xmlui/handle/123456789/19580
ISSN: 0253-5106
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