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Title: | Thermoanalyticil Studies of Some Schiff Base Polymers and Their Metal Chelates |
Authors: | M. Y. KHUHAWAR A. H. CHANNAR S. W. SHAH |
Issue Date: | 4-Mar-2000 |
Publisher: | The Chemical Society Of Pakistan |
Citation: | Khuhawar, M. Y., Channar, A. H., & Shah, S. W. (2000). Thermoanalytical studies of some Schiff base polymers and their metal chelates. JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 22(1), 14-17. |
Abstract: | Thermogravimetry (TO) and differential thermal analysis (DTA) of poly S,S·· methylene-bis-salicylaldehyde-tetramethylenediimine (PMSATen). poly 5,5' -methylene-bissalicylaldehyde-meso-stilbenediimine (meso-PMSAS). poly 5, 5'-methylene-bis-salicylaldehydedl·stilbenediimine (dl-PMSAS). Poly 5, 5.methylene-bis-salicylaldehycle-2.6-diiminopyridine (PMSAP), and their copper (II) and nickel (II) chelates were recorded in nitrogen atmosphere up to 800 °C. Loss in weight occurs in two to three stages. The polymers and their nickel chelates indicate better thermal stability as compared to their corresponding copper complexes. DT A shows a series of endotherms with maximum in the range of 400-700 °C. |
URI: | http://142.54.178.187:9060/xmlui/handle/123456789/19580 |
ISSN: | 0253-5106 |
Appears in Collections: | Issue 01 |
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1685-7592-1-CE.htm | 123 B | HTML | View/Open |
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