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http://142.54.178.187:9060/xmlui/handle/123456789/19662| Title: | Synthesis and Characterization of Zinc and Cadmium complexes with Deoxyalliin |
| Authors: | SHAHBAZ NAZIR JAMIL ANWAR MUNAWAR ALI, MUNAWAR |
| Issue Date: | 20-Aug-2009 |
| Publisher: | HEJ Research Institute of Chemistry, University of Karachi, Karachi. |
| Citation: | Nazir, S., Anwar, J., & Munawar, M. A. (2009). Synthesis and Characterization of Zinc and Cadmium complexes with Deoxyalliin. J. Chem. Soc. Pak, 31(4), 615. |
| Abstract: | Zinc and Cadmium complexes with the amino acid, deoxyalliin (S-Allyl Cysteine), having the formulae [Zn(C6H10O2NS)2] and [Cd(C6H10O2NS)2] were synthesized and characterized by elemental analysis, FT-IR, thermogravimetry-FT-IR analysis and X-ray diffraction studies. FT-IR shows the coordination through the nitrogen atom of the amino group and the oxygen of carboxylic group. Thermogravimetric analysis shows the decomposition of the complexes in two steps. X-ray diffraction analysis reveals the crystalline structure of complexes to be monoclinic (For zinc complex, a = 8.093, b = 20.126, c = 10.321, β = 103.20o, For cadmium complex, a = 15.276, b = 5.093, c = 8.991, β = 96.59o). Complexes are found to be polymeric with octahedral geometry around the metal atom. |
| URI: | http://142.54.178.187:9060/xmlui/handle/123456789/19662 |
| ISSN: | 0253-5106 |
| Appears in Collections: | Issue 04 |
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