Comparative Vapour Phase FTIR Studies and Vibrational Assignment of Cyclopentadienyl-manganese-tricarbonyl and Methylcyclopentadienyl-manganese-tricarbonyl

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Title:	Comparative Vapour Phase FTIR Studies and Vibrational Assignment of Cyclopentadienyl-manganese-tricarbonyl and Methylcyclopentadienyl-manganese-tricarbonyl
Authors:	Zahid Mahmood Syeda Robina, Gillani
Issue Date:	20-Aug-2009
Publisher:	HEJ Research Institute of Chemistry, University of Karachi, Karachi.
Citation:	Mahmood, Z., & Gilani, S. R. (2009). Comparative vapour phase ftir studies and vibrational assignment of cyclopentadienyl-manganese-tricarbonyl and methylcyclopentadienyl-manganese-tricarbonyl. Journal of the Chemical Society of Pakistan, 31.
Abstract:	The FTIR spectra in solution and vapour phase of the compounds, cyclopentadienyl manganese tricarbonyl (η-C₅H₅)Mn(CO)₃and methylcyclopentatadieny l manganese tricarbonyl (η-C₅H₄CH₃)Mn(CO)₃ were measured in the region 4000-400 cm⁻¹. An Assignment is offered in which the normal modes are described in term of "Local symmetry". This assignment has been discussed in terms of previous assignment given for (in Liquid phase and nujoll mull) other η-cyclopentadienyl and related compounds including ferrocene, dimethyl ferrocene, benzenechromium ticarbonyl and toulene chromium tricarbonyl.
URI:	http://142.54.178.187:9060/xmlui/handle/123456789/19824
ISSN:	0253-5106
Appears in Collections:	Issue 04

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