Please use this identifier to cite or link to this item: http://localhost:80/xmlui/handle/123456789/19919
Title: MIXED LIGAND COPPER(II) COMPLEXES OF PYRROLIDINEDITHIOCARBAMATE AND DIAMINES
Authors: SAEED AHMAD
MASOOD SARWAR
SAJJAD AHMAD
SAQIB ALI
KHURRAM
Issue Date: 20-Aug-2010
Publisher: HEJ Research Institute of Chemistry, University of Karachi, Karachi.
Citation: Ahmad, S., Sarwar, M., & Ali, S. (2010). Mixed ligand copper (II) complexes of pyrrolidine dithiocarbamate and diamines. Journal of the Chemical Society of Pakistan, 32.
Abstract: Copper(II) complexes of pyrrolidinedithiocarbamate (PDTC) and diamines having the general formula, [Cu(diamine)(PDTC)]Cl, [Cu(diamine)Cl₂][Cu(PDTC)Cl] or [Cu₂(di-amine)(PDTC)₂Cl₂] (diamine = 1,3-diaminopropane, N,N/-dimethylethylenediamine, N,N,N/,N/-tetramethylethylenediamine and 1,2-phenylenediamine) have been prepared and characterized by IR spectroscopy and thermal analysis. The results of thermal analysis are consistent with the proposed composition of the complexes. The IR data suggest that coordination of the pyrrolidinedi-thiocarbamate (PDTC) takes place through the two sulfur atoms in a symmetrical bidentate fashion.
URI: http://142.54.178.187:9060/xmlui/handle/123456789/19919
ISSN: 0253-5106
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