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http://142.54.178.187:9060/xmlui/handle/123456789/19920| Title: | Novel Ru-Complex of Methyldiphenylcyclopentadienylide |
| Authors: | SYEDA ROBINA GILANI ZAID MAHMOOD |
| Issue Date: | 20-Aug-2010 |
| Publisher: | HEJ Research Institute of Chemistry, University of Karachi, Karachi. |
| Citation: | Gilani, S. R., & Mehmood, A. (2010). Novel Ru-complex of methyldiphenylcyclopentadienylide. Journal of the Chemical Society of Pakistan, 32(4), 449-461. |
| Abstract: | Ylide CpPMePh₂ was synthesized by the deprotonation of Ylide salt of iodide by using different deprotonating agent like n butyl Li, NaH, (CH₃)₂N Li, isopropyl Li and ((CH₃)₃Si)₂N.Li. Out of all these deprotonating agents only ((CH₃)₃Si)₂N.Li gave pure and better yield. Its complex of Ru was synthesized. A RuCl₂(PPh₃)₃complex reacted with the freshly synthesized Ylide gave successful required ruthenium complex. The synthesized [Ru(PPh₃)₃(CpPMePh₂)₂]Cl₂ complex was analyzed and verified by ₁H and ₃₁P NMR. |
| URI: | http://142.54.178.187:9060/xmlui/handle/123456789/19920 |
| ISSN: | 0253-5106 |
| Appears in Collections: | Issue 04 |
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|---|---|---|---|---|
| ViewByVolume.aspx?v=8&i=VOLUME%2032,%20NO4,%20AUG%202010.htm | 147 B | HTML | View/Open |
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