Novel Ru-Complex of Methyldiphenylcyclopentadienylide

Please use this identifier to cite or link to this item: http://localhost:80/xmlui/handle/123456789/19920

Title:	Novel Ru-Complex of Methyldiphenylcyclopentadienylide
Authors:	SYEDA ROBINA GILANI ZAID MAHMOOD
Issue Date:	20-Aug-2010
Publisher:	HEJ Research Institute of Chemistry, University of Karachi, Karachi.
Citation:	Gilani, S. R., & Mehmood, A. (2010). Novel Ru-complex of methyldiphenylcyclopentadienylide. Journal of the Chemical Society of Pakistan, 32(4), 449-461.
Abstract:	Ylide CpPMePh₂ was synthesized by the deprotonation of Ylide salt of iodide by using different deprotonating agent like n butyl Li, NaH, (CH₃)₂N Li, isopropyl Li and ((CH₃)₃Si)₂N.Li. Out of all these deprotonating agents only ((CH₃)₃Si)₂N.Li gave pure and better yield. Its complex of Ru was synthesized. A RuCl₂(PPh₃)₃complex reacted with the freshly synthesized Ylide gave successful required ruthenium complex. The synthesized [Ru(PPh₃)₃(CpPMePh₂)₂]Cl₂ complex was analyzed and verified by ₁H and ₃₁P NMR.
URI:	http://142.54.178.187:9060/xmlui/handle/123456789/19920
ISSN:	0253-5106
Appears in Collections:	Issue 04

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