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http://142.54.178.187:9060/xmlui/handle/123456789/20023| Title: | Characterization and Crystal Structure of Trans-Dichloro(Bis-Thiocarbohydrazide) Cadmium(II) |
| Authors: | MOHAMMAD HAKIMI NOUROLLAH FEIZI FATEMEH ABBASI REZA TAKJOO ESTHER SCHUH FABIAN MOHR |
| Keywords: | Thiocarbohydrazide Cadmium (II); Hydrogen bonding Crystal structure |
| Issue Date: | 20-Jun-2012 |
| Publisher: | HEJ Research Institute of Chemistry, University of Karachi, Karachi. |
| Citation: | Hakimi, M., Feizi, N., Abbasi, F., Takjoo, R., Schuh, E., & Mohr, F. (2012). Characterization and crystal structure of trans-dichloro (bis-thiocarbohydrazide) cadmium (II). Journal of the Chemical Society of Pakistan, 34(3). |
| Abstract: | The preparation and spectroscopic characterization of trans-dichloro(bisthiocarbohydrazide) cadmium(II) using UV–Vis, Raman and IR spectroscopies is reported is reported in this paper. Molecular structure of the complex was determined by single-crystal X-ray diffraction. The compound crystallizes in the monoclinic crystal system, space group P2₁/n, Z = 4, V = 594.91(5) ų with unit cell parameters a = 8.6136(4) Å, b = 5.7881(3) Å, c = 12.0980(6) Å and β = 99.487(5) º. The cadmium (II) ion is bound to sulfur and nitrogen atoms of two thiocarbohydrazide ligands as well as two chloride ions in an octahedral geometry about Cd. |
| URI: | http://142.54.178.187:9060/xmlui/handle/123456789/20023 |
| ISSN: | 0253-5106 |
| Appears in Collections: | Issue 03 |
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| ViewByVolume.aspx?v=176&i=VOLUME%2034,%20NO3,%20JUN%202012.htm | 149 B | HTML | View/Open |
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