Characterization and Crystal Structure of   Trans-Dichloro(Bis-Thiocarbohydrazide) Cadmium(II)

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Title:	Characterization and Crystal Structure of Trans-Dichloro(Bis-Thiocarbohydrazide) Cadmium(II)
Authors:	MOHAMMAD HAKIMI NOUROLLAH FEIZI FATEMEH ABBASI REZA TAKJOO ESTHER SCHUH FABIAN MOHR
Keywords:	Thiocarbohydrazide Cadmium (II); Hydrogen bonding Crystal structure
Issue Date:	20-Jun-2012
Publisher:	HEJ Research Institute of Chemistry, University of Karachi, Karachi.
Citation:	Hakimi, M., Feizi, N., Abbasi, F., Takjoo, R., Schuh, E., & Mohr, F. (2012). Characterization and crystal structure of trans-dichloro (bis-thiocarbohydrazide) cadmium (II). Journal of the Chemical Society of Pakistan, 34(3).
Abstract:	The preparation and spectroscopic characterization of trans-dichloro(bisthiocarbohydrazide) cadmium(II) using UV–Vis, Raman and IR spectroscopies is reported is reported in this paper. Molecular structure of the complex was determined by single-crystal X-ray diffraction. The compound crystallizes in the monoclinic crystal system, space group P2₁/n, Z = 4, V = 594.91(5) Å³ with unit cell parameters a = 8.6136(4) Å, b = 5.7881(3) Å, c = 12.0980(6) Å and β = 99.487(5) º. The cadmium (II) ion is bound to sulfur and nitrogen atoms of two thiocarbohydrazide ligands as well as two chloride ions in an octahedral geometry about Cd.
URI:	http://142.54.178.187:9060/xmlui/handle/123456789/20023
ISSN:	0253-5106
Appears in Collections:	Issue 03

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