Regiospecific Mno2 Catalyzed Hydration of Phenylmethylene Malononitriles to Cyanophenylacrylamides by Oximes

Please use this identifier to cite or link to this item: http://localhost:80/xmlui/handle/123456789/20032

Title:	Regiospecific Mno2 Catalyzed Hydration of Phenylmethylene Malononitriles to Cyanophenylacrylamides by Oximes
Authors:	ABDUL RAUF FAISAL SALEEM AWAN SAIRA MUMTAZ AHSAN SHARIF EJAZ AHMED MUHAMMAD ARSHAD FARZANA KAUSAR GHAZALA YASMIN ASHFAQ MAHMOOD QURESHI
Issue Date:	20-Jun-2012
Publisher:	HEJ Research Institute of Chemistry, University of Karachi, Karachi.
Citation:	Rauf, A., Awan, F. S., Mumtaz, S., Sharif, A., Ahmed, E., Arshad, M., ... & Qureshi, A. M. (2012). Regiospecific MnO2 Catalyzed Hydration of Phenylmethylene Malononitriles to Cyanophenylacrylamides by Oximes. Journal of the Chemical Society of Pakistan, 34(3).
Abstract:	A novel and convenient method for the regiospecific hydration of phenylmethylene malononitriles to cyanoacrylamides was developed; Scope of the method and reaction conditions were optimized extensively, the method was found to be extremely successful in hydration of anti nitrile to phenyl group only in phenylmethylene malononitriles. This regiospecificity is owed mainly to steric factors.
URI:	http://142.54.178.187:9060/xmlui/handle/123456789/20032
ISSN:	0253-5106
Appears in Collections:	Issue 03

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